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Physics News Update
Number 464, December 27, 1999 by Phillip F. Schewe and Ben Stein

SUPERCONDUCTING BALLS, a new phenomenon, have been observed by physicists at Southern Illinois University. Rongjia Tao (618-536-2117, rtao@physics.siu.edu) and his colleagues began by wanting to observe the motion of micron-sized copper oxide (e.g., Br-Sr-Ca-Cu-O) superconducting particles (suspended in liquid nitrogen) in an electric field running between two electrodes. Metal particles in this situation would bounce between the two electrodes or tend to line up; after all, an electric field helps to define a preferred direction in space. The superconducting particles ignored this hint and, to the researchers' great surprise, formed themselves into a ball. The ball, about .25 mm across and containing over a million particles, formed quickly and was quite sturdy, surviving constant collisions with the electrodes (see figure at Physics News Graphics).

What binds the ball together against the dictates of the rectilinear field? Tao and his collaborator, Princeton theorist Philip Anderson, have concluded that the effect is an artifact of superconductivity (the same particles, above their superconducting transition temperature, do not ball up but instead queue into lines), perhaps something to do with the way in which the surface energy of the particle ensemble is reduced by self-assembly into a ball. This unprecedented new surface energy is related to the acquired surface charges on the particles and the reactions among the layers of the balls.

Granular properties of the particles might also play a role in the process and in the ball's internal structure, but this is difficult to gauge since the inter-particle interactions (frictional dissipation being the hallmark of granular materials) are mitigated by the liquid nitrogen needed in the experiment to neutralize gravity. A way around this is to do the experiment in the microgravity of space. The basic scientific novelty of this new phenomenon is paramount, but Tao is also turning his attention to possible applications in the area of superconducting thin films and unusual forms of wetting. (Tao et al., Physical Review Letters, 27 December 1999; for the text see Physics News Select Articles.)

TWO-DIMENSIONAL COLLOIDAL CRYSTALS SEEMINGLY DEFY COULOMB'S LAW as they form, experiments have shown. A colloidal crystal is a regular arrangement of tiny particles suspended in a liquid. Three-dimensional examples have long been known. Now free-floating 2D "crystallites" of colloidal particles, lashed together by bilayer membranes similar to those surrounding living cells, have been created, offering intriguing possibilities for using them as templates for artificial biomaterials and industrial catalysts.

University of Pennsylvania researchers (Laurence Ramos, now at Universite de Montpellier, France, ramos@gdpc.univ-montp2.fr) created the system by adding negatively charged latex beads to a suspension of positively charged soaplike (surfactant) membranes in water. As expected, initially the beads avidly stuck to the membranes. To the researchers' surprise, though, in many cases the beads formed rafts floating on the membrane. Outside the raft the membrane actually repelled additional beads, even though they were highly oppositely charged.

The researchers argued that the source of this paradoxical behavior lay in the migration of negative ions trapped on the side of the membrane opposite to the beads. With time the fluid rafts solidify into rigid, flat crystallites, near-perfect 2D crystalline structures some tens of microns on a side. (Ramos et al., Science, 17 December 1999; and Aranda-Espinoza et al., 16 June.)