TWO-DIMENSIONAL COLLOIDAL CRYSTALS SEEMINGLY DEFY COULOMB'S LAW as they form, experiments have shown. A colloidal crystal is a regular arrangement of tiny particles suspended in a liquid. Three-dimensional examples have long been known. Now free-floating 2D "crystallites" of colloidal particles, lashed together by bilayer membranes similar to those surrounding living cells, have been created, offering intriguing possibilities for using them as templates for artificial biomaterials and industrial catalysts. University of Pennsylvania researchers (Laurence Ramos, now at Universite de Montpellier, France, ramos@gdpc.univ-montp2.fr) created the system by adding negatively charged latex beads to a suspension of positively charged soaplike (surfactant) membranes in water. As expected, initially the beads avidly stuck to the membranes. To the researchers' surprise, though, in many cases the beads formed rafts floating on the membrane. Outside the raft the membrane actually repelled additional beads, even though they were highly oppositely charged.
The researchers argued that the source of this paradoxical behavior lay in the migration of negative ions trapped on the side of the membrane opposite to the beads. With time the fluid rafts solidify into rigid, flat crystallites, near-perfect 2D crystalline structures some tens of microns on a side. (Ramos et al., Science, 17 December 1999; and Aranda-Espinoza et al., 16 June.)